作者z3131669 (111)
看板Chemistry
標題[學科] 幾題物化問答題
時間Sun May 15 18:39:17 2011
1. Describe the main featur,including advantages and disadvantages,of the
following experimental methods for determining the rate law of a reaction:
the isolation method,the initial rates,and fitting data to integrated rate
law expressions.
2. Distinguish between kinetic and thermodynamic control of a reaction.
Suggest criteria for expecting one rather than the other.
補上一題推導題
The reaction mechanism for the decomposition of A2
A2 <==> A + A (fast)
A + B －> P (slow)
involve an intermediate A. Deduce the rate law for the reaction in two ways
by (a) assuming a pre-equilibrium and (b) making a steady-state approximation.
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※ 編輯: z3131669 來自: 123.240.108.175 (05/15 18:45)