作者kissinwang (兔兔世界的王子)
看板Biotech
标题[期刊] chitosan and chitosan MW. review
时间Wed Nov 14 16:24:54 2007
这篇期刊的方向/至少
30字, 希望能够写关於期刊大致内容方向等]
1. 这篇文章大概描述(30字)....
Starting from a chitosan sample with a degree of deacetylation of 71%, three
separate sample sets were generated by successive deacetylation and
reacetylation processes. The degree of deacetylation of samples was
determined by UV spectrometry supported by thermogravimetric analysis. The
molecular weight of chitosan samples was determined in a solvent system of
0.25 M CH3COOH/0.25 M CH3COONa, using viscometry and gel permeation
chromatography (GPC) with a TSK-gel column. The first set of samples had a
similar degree of deacetylation (DDA) but differing molecular weights. The
second set of samples had a similar molecular weight but differing degrees of
deacetylation. The Mark-Houwink-Sakurada constants used for the determination
of viscosity average molecular weight and the universal calibration of the
GPC system were K = 1.40 x 10(-4) dL/g and a = 0.83. Results showed that
molecular weights determined from both techniques are in good accord only at
lower degrees of deacetylation. This may be attributed to the fact that the
chemical structure of chitosan samples could have been largely altered with
increasing or decreasing degree of deacetylation. Nevertheless, the trend
with which the molecular weights vary with the deacetylation time is
consistent over a limited DDA range. A literature review of molecular weight
analysis of chitosan is included.
直接贴摘要好像太混了,简单来说这是一篇PAPER REVIEW 有关几丁质和几丁聚糖,
内容我没有看到,不过大多数的人作法都是用黏度来做相对分子量,不过我比较龟毛
看到上面有GPC~~这是我目前仅知的唯一做绝对分子量的方法。
[
期刊名称 与 标题卷号年份等资讯]
作者,出版年:Knaul, J. Z.
Kasaai, M. R.
Bui, V. T.
Creber, K. A. M.
1998
篇 名:Characterization of deacetylated chitosan and chitosan
molecular weight review
期刊名(卷期):Canadian Journal of Chemistry-Revue Canadienne De Chimie
76(11)
页 数:1699-1706
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