※ 引述《a1014210 (rainbow)》之铭言： : 根据其定义为具有直接 金属-有机配位基键结的化合物 : 这真的很拢统不适很明白阿? : 难道只要有C接上金属那就都属於有机金属吗? 有机金属的定义很广 而且众说纷纭 你问十个做有机金属的老师可能都会给你十种答案 那就来看期刊"Organometallics"里面给作者的指引吧 http://pubs.acs.org/paragonplus/submission/orgnd7/orgnd7_authguide.pdf For the purposes of this journal, an "organometallic" compound will be defined as one in which there is a bonding interaction (ionic or covalent, localized or delocalized) between one or more carbon atoms of an organic group or molecule and a main group, transition, lanthanide, or actinide metal atom (or atoms). 对这个期刊的目标而言，"有机金属"化合物被定义为化合物里有一个或多个碳与主族元素 .过渡元素.镧系金属.锕系金属之间有键结作用力(离子或共价，定域化或离域化) Following longstanding tradition, organic derivatives of the metalloids (boron, silicon, germanium, arsenic, and tellurium) will be included in this definition. 遵循长久以来的传统，类金属(B.Si.Ge.As.Te)的有机衍生物皆在此定义里。 Furthermore, manuscripts dealing with metal-containing compounds that do not contain metal–carbon bonds will be considered if there is a close relationship between the subject matter and the principles and practice of organometallic chemistry. 更进一步，稿件里的金属化合物若不包含金属-碳键，但拥有与有机金属化学主旨与应用 紧密相关，也可以被列入考量。 Such compounds may include, inter alia, representatives from the following classes: molecular metal hydrides; metal alkoxides, thiolates, amides, and phosphides; metal complexes containing organo-group 15 and 16 ligands; metal nitrosyls. Papers dealing with certain aspects of organophosphorus, organoselenium, and organosulfur chemistry also will be considered. 这些化合物的代表性例子包含了thiolates.amides和phosphides。包含15族.16族元素 ligands的金属错合物，一氧化氮错合物。包括磷化物.硒化物.硫化物的化学文章也是 被列入考量的。 俊毅Bird Man --

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